{"id":6154,"date":"2024-10-18T17:33:44","date_gmt":"2024-10-18T09:33:44","guid":{"rendered":"https:\/\/www.51dea.com\/archives\/6154"},"modified":"2024-10-18T17:33:44","modified_gmt":"2024-10-18T09:33:44","slug":"%e7%8e%af%e5%b7%b1%e8%83%ba%e5%9c%a8%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e5%8f%8d%e5%ba%94%e4%b8%ad%e7%9a%84%e5%82%ac%e5%8c%96%e4%bd%9c%e7%94%a8%e5%8f%8a%e5%85%b6%e9%80%89%e6%8b%a9%e6%80%a7%e7%a0%94","status":"publish","type":"post","link":"https:\/\/www.51dea.com\/archives\/6154","title":{"rendered":"\u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u9009\u62e9\u6027\u7814\u7a76"},"content":{"rendered":"
\u73af\u5df1\u80fa\uff08Cyclohexylamine, CHA\uff09\u4f5c\u4e3a\u4e00\u79cd\u5e38\u89c1\u7684\u6709\u673a\u5316\u5408\u7269\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u4e2d\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u672c\u6587\u7efc\u8ff0\u4e86\u73af\u5df1\u80fa\u5728\u4e0d\u540c\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u7279\u522b\u662f\u5176\u5bf9\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u901a\u8fc7\u8be6\u7ec6\u5206\u6790\u4e0d\u540c\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u5b9e\u9a8c\u6570\u636e\uff0c\u63a2\u8ba8\u4e86\u73af\u5df1\u80fa\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u548c\u6548\u7387\uff0c\u65e8\u5728\u4e3a\u6709\u673a\u5408\u6210\u5316\u5b66\u5bb6\u63d0\u4f9b\u7406\u8bba\u6307\u5bfc\u548c\u6280\u672f\u652f\u6301\u3002<\/p>\n
\u73af\u5df1\u80fa\uff08Cyclohexylamine, CHA\uff09\u662f\u4e00\u79cd\u65e0\u8272\u6db2\u4f53\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4e00\u5b9a\u7684\u4eb2\u6838\u6027\uff0c\u8fd9\u4e9b\u6027\u8d28\u4f7f\u5176\u5728\u591a\u79cd\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u5bfb\u627e\u9ad8\u6548\u3001\u73af\u5883\u53cb\u597d\u7684\u50ac\u5316\u5242\u6210\u4e3a\u4e86\u5316\u5b66\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u4e4b\u4e00\u3002\u73af\u5df1\u80fa\u7531\u4e8e\u5176\u4f4e\u6210\u672c\u3001\u6613\u83b7\u5f97\u53ca\u8f83\u4f4e\u7684\u6bd2\u6027\uff0c\u6210\u4e3a\u4e86\u7814\u7a76\u8005\u4eec\u5173\u6ce8\u7684\u7126\u70b9\u3002\u672c\u6587\u5c06\u7cfb\u7edf\u5730\u56de\u987e\u73af\u5df1\u80fa\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\uff0c\u91cd\u70b9\u8ba8\u8bba\u5176\u5728\u4e0d\u540c\u53cd\u5e94\u7c7b\u578b\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u53ca\u5176\u9009\u62e9\u6027\u3002<\/p>\n
\u73af\u5df1\u80fa\u5728\u9170\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5c24\u5176\u662f\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u3002\u73af\u5df1\u80fa\u901a\u8fc7\u5f62\u6210\u7a33\u5b9a\u7684\u4e2d\u95f4\u4f53\uff0c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\uff0c\u4ece\u800c\u52a0\u901f\u53cd\u5e94\u901f\u7387\u5e76\u63d0\u9ad8\u4ea7\u7387\u3002<\/p>\n
3.1.1 \u7fa7\u9178\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94<\/strong><\/p>\n \u88681\u5c55\u793a\u4e86\u4e0d\u540c\u6761\u4ef6\u4e0b\u73af\u5df1\u80fa\u5bf9\u7fa7\u9178\u4e0e\u9187\u916f\u5316\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n 3.1.2 \u9170\u6c2f\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94<\/strong><\/p>\n \u73af\u5df1\u80fa\u5728\u9170\u6c2f\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94\u4e2d\u4e5f\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\u3002\u88682\u5217\u51fa\u4e86\u51e0\u4e2a\u5178\u578b\u7684\u6848\u4f8b\u3002<\/p>\n \u73af\u5df1\u80fa\u5728\u52a0\u6210\u53cd\u5e94\u4e2d\u540c\u6837\u8868\u73b0\u51fa\u663e\u8457\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u7279\u522b\u662f\u5728\u919b\u3001\u916e\u7c7b\u5316\u5408\u7269\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u53cd\u5e94\u4e2d\u3002<\/p>\n 3.2.1 \u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n \u88683\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u52a0\u6210\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n 3.2.2 \u916e\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n \u73af\u5df1\u80fa\u5728\u916e\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94\u4e2d\u4e5f\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\u3002\u88684\u5217\u51fa\u4e86\u51e0\u4e2a\u5178\u578b\u6848\u4f8b\u3002<\/p>\n \u73af\u5df1\u80fa\u5728\u8fd8\u539f\u53cd\u5e94\u4e2d\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u5728\u4f7f\u7528\u91d1\u5c5e\u6c22\u5316\u7269\u5982\u787c\u6c22\u5316\u94a0\u6216\u6c22\u5316\u94dd\u9502\u65f6\u3002\u73af\u5df1\u80fa\u7684\u5b58\u5728\u6709\u52a9\u4e8e\u7a33\u5b9a\u91d1\u5c5e\u6c22\u5316\u7269\uff0c\u9632\u6b62\u5176\u5206\u89e3\uff0c\u5e76\u63d0\u9ad8\u76ee\u6807\u4ea7\u7269\u7684\u9009\u62e9\u6027\u3002<\/p>\n 3.3.1 \u787c\u6c22\u5316\u94a0\u8fd8\u539f\u53cd\u5e94<\/strong><\/p>\n \u88685\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u787c\u6c22\u5316\u94a0\u8fd8\u539f\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n 3.3.2 \u6c22\u5316\u94dd\u9502\u8fd8\u539f\u53cd\u5e94<\/strong><\/p>\n \u73af\u5df1\u80fa\u5728\u6c22\u5316\u94dd\u9502\u8fd8\u539f\u53cd\u5e94\u4e2d\u540c\u6837\u8868\u73b0\u51fa\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\u3002\u88686\u5217\u51fa\u4e86\u51e0\u4e2a\u5178\u578b\u6848\u4f8b\u3002<\/p>\n \u73af\u5df1\u80fa\u7684\u9009\u62e9\u6027\u4e3b\u8981\u4f53\u73b0\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n \u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\uff0c\u7279\u5b9a\u6784\u578b\u7684\u73af\u5df1\u80fa\u80fd\u591f\u5f15\u5bfc\u53cd\u5e94\u671d\u5411\u67d0\u4e00\u7acb\u4f53\u5f02\u6784\u4f53\u65b9\u5411\u8fdb\u884c\u3002\u4f8b\u5982\uff0c\u5728\u624b\u6027\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u624b\u6027\u73af\u5df1\u80fa\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u4ea7\u7269\u7684\u5bf9\u6620\u4f53\u8fc7\u91cf\uff08ee\u503c\uff09\u3002<\/p>\n 4.1.1 \u624b\u6027\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n \u88687\u5c55\u793a\u4e86\u624b\u6027\u73af\u5df1\u80fa\u5bf9\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/p>\n \u5bf9\u4e8e\u542b\u6709\u591a\u4e2a\u53cd\u5e94\u4f4d\u70b9\u7684\u5e95\u7269\uff0c\u73af\u5df1\u80fa\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6761\u4ef6\u6765\u5b9e\u73b0\u7279\u5b9a\u5b98\u80fd\u56e2\u7684\u9009\u62e9\u6027\u8f6c\u5316\u3002\u4f8b\u5982\uff0c\u5728\u591a\u5b98\u80fd\u56e2\u5316\u5408\u7269\u7684\u916f\u5316\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u53ef\u4ee5\u4f18\u5148\u4fc3\u8fdb\u67d0\u4e00\u7279\u5b9a\u7fa7\u9178\u57fa\u56e2\u7684\u916f\u5316\u3002<\/p>\n 4.2.1 \u591a\u5b98\u80fd\u56e2\u5316\u5408\u7269\u7684\u916f\u5316\u53cd\u5e94<\/strong><\/p>\n \u88688\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u5316\u5b66\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/p>\n \u5728\u591a\u53d6\u4ee3\u57fa\u5e95\u7269\u7684\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u6709\u52a9\u4e8e\u63a7\u5236\u65b0\u952e\u5f62\u6210\u7684\u4f4d\u70b9\uff0c\u4ece\u800c\u5f97\u5230\u9884\u671f\u7684\u4ea7\u7269\u3002\u4f8b\u5982\uff0c\u5728\u591a\u53d6\u4ee3\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u73af\u5df1\u80fa\u53ef\u4ee5\u5f15\u5bfc\u4eb2\u6838\u8bd5\u5242\u4f18\u5148\u653b\u51fb\u67d0\u4e00\u7279\u5b9a\u4f4d\u70b9\u3002<\/p>\n 4.3.1 \u591a\u53d6\u4ee3\u919b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u52a0\u6210\u53cd\u5e94<\/strong><\/p>\n \u88689\u5c55\u793a\u4e86\u73af\u5df1\u80fa\u5bf9\u533a\u57df\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/p>\n\n\n
\n \n\u53cd\u5e94\u6761\u4ef6<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u65e0\u50ac\u5316\u5242<\/td>\n –<\/td>\n 24<\/td>\n 45<\/td>\n<\/tr>\n \n \u73af\u5df1\u80fa<\/td>\n 5<\/td>\n 12<\/td>\n 80<\/td>\n<\/tr>\n \n \u73af\u5df1\u80fa<\/td>\n 10<\/td>\n 8<\/td>\n 85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n\n
\n \n\u9170\u6c2f<\/th>\n \u9187<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u4e59\u9170\u6c2f<\/td>\n <\/td>\n 5<\/td>\n 90<\/td>\n<\/tr>\n \n \u4e19\u9170\u6c2f<\/td>\n <\/td>\n 5<\/td>\n 88<\/td>\n<\/tr>\n \n \u4e01\u9170\u6c2f<\/td>\n <\/td>\n 5<\/td>\n 85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 3.2 \u52a0\u6210\u53cd\u5e94<\/h5>\n
\n\n
\n \n\u919b<\/th>\n \u4eb2\u6838\u8bd5\u5242<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u7532\u919b<\/td>\n \u7532\u9187\u94a0<\/td>\n 5<\/td>\n 75<\/td>\n<\/tr>\n \n \u7532\u919b<\/td>\n \u94a0<\/td>\n 5<\/td>\n 80<\/td>\n<\/tr>\n \n \u4e19\u919b<\/td>\n \u94a0<\/td>\n 5<\/td>\n 78<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n\n
\n \n\u916e<\/th>\n \u4eb2\u6838\u8bd5\u5242<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u4e19\u916e<\/td>\n \u94a0<\/td>\n 3<\/td>\n 82<\/td>\n<\/tr>\n \n \u73af\u5df1\u916e<\/td>\n \u94a0<\/td>\n 4<\/td>\n 88<\/td>\n<\/tr>\n \n \u4e01\u916e<\/td>\n \u94a0<\/td>\n 3<\/td>\n 80<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 3.3 \u8fd8\u539f\u53cd\u5e94<\/h5>\n
\n\n
\n \n\u5e95\u7269<\/th>\n \u8fd8\u539f\u5242<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u4e19\u916e<\/td>\n \u787c\u6c22\u5316\u94a0<\/td>\n 5<\/td>\n 90<\/td>\n<\/tr>\n \n \u4e01\u916e<\/td>\n \u787c\u6c22\u5316\u94a0<\/td>\n 5<\/td>\n 88<\/td>\n<\/tr>\n \n \u73af\u5df1\u916e<\/td>\n \u787c\u6c22\u5316\u94a0<\/td>\n 5<\/td>\n 92<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n\n
\n \n\u5e95\u7269<\/th>\n \u8fd8\u539f\u5242<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u4e19\u916e<\/td>\n \u6c22\u5316\u94dd\u9502<\/td>\n 5<\/td>\n 95<\/td>\n<\/tr>\n \n \u4e01\u916e<\/td>\n \u6c22\u5316\u94dd\u9502<\/td>\n 5<\/td>\n 93<\/td>\n<\/tr>\n \n \u73af\u5df1\u916e<\/td>\n \u6c22\u5316\u94dd\u9502<\/td>\n 5<\/td>\n 97<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 4. \u73af\u5df1\u80fa\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027<\/h4>\n
4.1 \u7acb\u4f53\u9009\u62e9\u6027<\/h5>\n
\n\n
\n \n\u624b\u6027\u919b<\/th>\n \u4eb2\u6838\u8bd5\u5242<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n ee\u503c (%)<\/th>\n<\/tr>\n<\/thead>\n \n (S)-\u7532\u919b<\/td>\n \u7532\u9187\u94a0<\/td>\n 5<\/td>\n 75<\/td>\n 92<\/td>\n<\/tr>\n \n (R)-\u7532\u919b<\/td>\n \u7532\u9187\u94a0<\/td>\n 5<\/td>\n 73<\/td>\n 90<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 4.2 \u5316\u5b66\u9009\u62e9\u6027<\/h5>\n
\n\n
\n \n\u5e95\u7269<\/th>\n \u9187<\/th>\n \u50ac\u5316\u5242\u6d53\u5ea6 (mol%)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u9009\u62e9\u6027 (%)<\/th>\n<\/tr>\n<\/thead>\n \n \u4e8c\u7fa7\u9178<\/td>\n <\/td>\n 5<\/td>\n 85<\/td>\n 90<\/td>\n<\/tr>\n \n \u4e09\u7fa7\u9178<\/td>\n <\/td>\n 5<\/td>\n 80<\/td>\n 85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 4.3 \u533a\u57df\u9009\u62e9\u6027<\/h5>\n